Complete assignments of 1H and 13C NMR spectra of leucanthoside A, a new triterpenoid saponin from Cephalaria leucantha L.

D. Godevac; B. Mandić; V. Vajs; N. Menković; S. Macura; S. Milosavljević

doi:10.1002/mrc.1834

Complete assignments of ¹H and ¹³C NMR spectra of leucanthoside A, a new triterpenoid saponin from Cephalaria leucantha L.

D. Godevac, B. Mandić, V. Vajs, N. Menković, S. Macura, S. Milosavljević

Biochemistry and Molecular Biology

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Leucanthoside A, a new allose-containing triterpenoid saponin (1), was isolated from the aerial parts of Cephalaria leucantha L. Its structure was determined by electrospray ionization mass spectrometry and NMR spectroscopy. Complete assignments of the ¹H and ¹³C NMR chemical shifts were achieved by two-dimensional NMR experiments: DQF-COSY, NOESY, TOCSY, HSQC, DINE-HSQC, HMBC, ¹³C-¹H 2D-J-resolved spectroscopy, and 1,1-ADEQUATE.

Original language	English (US)
Pages (from-to)	731-735
Number of pages	5
Journal	Magnetic Resonance in Chemistry
Volume	44
Issue number	7
DOIs	https://doi.org/10.1002/mrc.1834
State	Published - Jul 2006

Keywords

2D NMR
C NMR
Cephalaria leucantha
H NMR
Leucanthoside A
NMR
Saponin

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)

Access to Document

10.1002/mrc.1834

Cite this

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title = "Complete assignments of 1H and 13C NMR spectra of leucanthoside A, a new triterpenoid saponin from Cephalaria leucantha L.",

abstract = "Leucanthoside A, a new allose-containing triterpenoid saponin (1), was isolated from the aerial parts of Cephalaria leucantha L. Its structure was determined by electrospray ionization mass spectrometry and NMR spectroscopy. Complete assignments of the 1H and 13C NMR chemical shifts were achieved by two-dimensional NMR experiments: DQF-COSY, NOESY, TOCSY, HSQC, DINE-HSQC, HMBC, 13C-1H 2D-J-resolved spectroscopy, and 1,1-ADEQUATE.",

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AU - Godevac, D.

AU - Mandić, B.

AU - Vajs, V.

AU - Menković, N.

AU - Macura, S.

AU - Milosavljević, S.

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AB - Leucanthoside A, a new allose-containing triterpenoid saponin (1), was isolated from the aerial parts of Cephalaria leucantha L. Its structure was determined by electrospray ionization mass spectrometry and NMR spectroscopy. Complete assignments of the 1H and 13C NMR chemical shifts were achieved by two-dimensional NMR experiments: DQF-COSY, NOESY, TOCSY, HSQC, DINE-HSQC, HMBC, 13C-1H 2D-J-resolved spectroscopy, and 1,1-ADEQUATE.

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KW - H NMR

KW - Leucanthoside A

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