Uranium(V) as an intermediate in the photochemical reduction of the uranyl ion with dicyclohexylsulphide

S. S. Sandhu; R. J. Singh; S. K. Chawla

doi:10.1016/1010-6030(90)87091-O

Uranium(V) as an intermediate in the photochemical reduction of the uranyl ion with dicyclohexylsulphide

S. S. Sandhu, R. J. Singh, S. K. Chawla

Laboratory Medicine and Pathology

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Abstract

Formation of uranium(V) was established using electronic absorption studies in the photochemical reduction of the uranyl ion by dicyclohexylsulphide in dry acetone medium. Low values of the quantum yields Φ(U(V)) were found. The Stern-Volmer quenching constant suggests a significant physical quenching contribution of the cyclohexyl group.

Original language	English (US)
Pages (from-to)	65-68
Number of pages	4
Journal	Journal of Photochemistry and Photobiology, A: Chemistry
Volume	52
Issue number	1
DOIs	https://doi.org/10.1016/1010-6030(90)87091-O
State	Published - May 10 1990

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Physics and Astronomy(all)

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title = "Uranium(V) as an intermediate in the photochemical reduction of the uranyl ion with dicyclohexylsulphide",

abstract = "Formation of uranium(V) was established using electronic absorption studies in the photochemical reduction of the uranyl ion by dicyclohexylsulphide in dry acetone medium. Low values of the quantum yields Φ(U(V)) were found. The Stern-Volmer quenching constant suggests a significant physical quenching contribution of the cyclohexyl group.",

author = "Sandhu, {S. S.} and Singh, {R. J.} and Chawla, {S. K.}",

note = "Funding Information: R. J. S. is grateful to the Council of Scientific and Industrial Research, New Delhi for financial assistance. Copyright: Copyright 2014 Elsevier B.V., All rights reserved.",

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AU - Sandhu, S. S.

AU - Singh, R. J.

AU - Chawla, S. K.

PY - 1990/5/10

Y1 - 1990/5/10

N2 - Formation of uranium(V) was established using electronic absorption studies in the photochemical reduction of the uranyl ion by dicyclohexylsulphide in dry acetone medium. Low values of the quantum yields Φ(U(V)) were found. The Stern-Volmer quenching constant suggests a significant physical quenching contribution of the cyclohexyl group.

AB - Formation of uranium(V) was established using electronic absorption studies in the photochemical reduction of the uranyl ion by dicyclohexylsulphide in dry acetone medium. Low values of the quantum yields Φ(U(V)) were found. The Stern-Volmer quenching constant suggests a significant physical quenching contribution of the cyclohexyl group.

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Uranium(V) as an intermediate in the photochemical reduction of the uranyl ion with dicyclohexylsulphide

Abstract

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